Surface chemistry and Electrode Design for High Performance Li-S battery
Beijing University of Chemical Technology
Abstract: Based on the reaction of 16Li + S8 ↔ 8Li2S, Li-S battery reaches a high theoretical energy density of 2600 Wh/kg, which is several times higher than that of traditional lithium ion batteries (LIBs). The low cost, high capacity as well as environment-benignity make Li-S battery as a strong candidate for next generation energy storage. However, the development of Li-S battery is severely hindered by several problems, including the low conductivity of sulfur cathode, volume variation during charge/discharge and dissolution of lithium polysulfide (LiPS). These drawbacks cause low utilization of sulfur and poor cycling performance of batteries. To overcome these obstacles, researchers pay attention to regulating the construction of sulfur cathode, using mesoporous materials, core-shell types carbon and graphene oxide etc. The carbon based materials have significant benefit on the conductivity of the electrode and suppress the polysulfide dissolution to some extent. But the nonpolar carbon intrinsically has poor interaction with LiPS and lithium sulfide. Moreover, the lithium dendrite growth and electrode pulverization during cycling give rise to lower columbic efficiency and safety risks. Hence, the polysulfide trapping chemistry, sulfur electrode design and Li mental electrode protection are the key factors contributing to the cycling performance and stability of Li-S battery.
Herein, we propose polar materials including inorganic mental oxides, metal phosphides and organic functional groups, which further hybrid with nano carbons to construct bifunctional host for sulfur electrode. On one hand, the polar sites can strongly absorb LiPS, so that the dissolution of LiPS and shuttling effect can be reduced. On the other hand, polysulfide after absorption can quickly reacted with electrons and Li-ions, therefore improving the reaction kinetics and eliminating the bulky “dead sulfur” formation. Consequently, the Li-S batteries with the high performance sulfur electrodes can stably run for over 1000 cycles. The mechanism of sulfur trapping chemistry was also revealed by XPS characterization and theoretical calculation.
In terms of Li metal anode, the huge volume variation during cycling cause electrode pulverization, which is especially serious when paired with high mass loading sulfur cathode. We demonstrate that nanostructuring is one of the key points to realize stable lithium metal anode. Different kinds of scaffold have been constructed with Li mental to reduce the volume variation and suppress dendrite growth. The lithiophilic treatment of scaffold leads to lithium uniformly deposit and nucleate on electrode surface. The dendrite-free lithium deposition also achieved through manipulation of Li-ions transport number by modifying a separator with metal–organic framework materials (MOFs).
Wen Liu engaged in inorganic materials synthesis and energy application
(lithium ion battery, electrochemical hydrogen production, etc.) since his PhD study
in Peking University. In his research, he deals with the synthesis and characterization
of electrode materials for batteries or electro-catalysis, and reveals the
structure-property relationship with advanced analysis methods. He is
especially interested in the surface chemistry of materials and heterostructures,
and their effect on the efficiency of energy storage or conversion. The related
works have been published in Nature Commun., PNAS, J. Am. Chem. Soc., Angew.
Chem., Nano Lett., Adv. Mater., Adv. Energy Mater., Nano Today, Nano Research,
J. Power Sources, J. Mater. Chem. A. and other international journals.